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Author | Viswanathan, Subha | |
Author | de Bettencourt-Dias, Ana | |
Date Accessioned | 2017-06-07T17:40:42Z | |
Date Available | 2017-06-07T17:40:42Z | |
Date of Issue | 2006 | |
ISSN | 0959-9428 | |
Identifier (URI) | http://hdl.handle.net/11714/1056 | |
Description | A luminescent 2-chloro-5-nitrobenzoic acid derivative of Eu(III) with a columnar structure has been isolated and characterized. This compound shows red emission in the solid state. Solutions of the ligand and Eu(III) in 1:1 stoichiometry are also luminescent with an excited state lifetime of 307.0�4 ms and a quantum yield of emission of 1.0%. This is to date the highest reported value of quantum yield of luminescence of Eu(III) sensitized by a nitrobenzoic acid derivative. The analogous solution for Tb(III) displays bright green luminescence with an excited state lifetime of 1.040�026 ms and a quantum yield of 3.7%. | |
Item Language | English(United States) | |
Rights | Copyright Not Evaluated | |
Source URI | https://dx.doi.org/10.1016/j.inoche.2006.01.022 | |
Title | 2-Chloro-5-nitrobenzoato complexes of Eu(III) and Tb(III) - A 1D coordination polymer and enhanced solution luminescence | |
Type | Citation | |
Identifier (DOI) | 10.1016/j.inoche.2006.01.022 | |
Journal Title | Inorganic Chemistry Communications |
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